The Diels–Alder cycloaddition of activated vinyl sulphoxides (1), that are readily obtained by a self-induced chiral oxidation, proceeds highly diastereoselectively to form the corresponding cycloadducts (4) that can be converted into 2-substituted norbornadienes(5) of high enantiomeric purity.
O. De Lucchi, C. Marchioro, G. Valle and G. Modena, J. Chem. Soc., Chem. Commun., 1985, 878 DOI: 10.1039/C39850000878
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