Racemic dihydrosecologanin aglucone (2) has been prepared via substituted cyclopentenolones in an efficient synthetic sequence involving a novel selective decarboalkoxylation of β-keto-esters as a key step.
R. T. Brown and M. F. Jones, J. Chem. Soc., Chem. Commun., 1985, 699 DOI: 10.1039/C39850000699
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