Alkenylsilanes, on treatment with iodosylbenzene activated by co-ordination of boron trifluoride–diethyl ether to the oxygen atom, give the corresponding alkynes in good to excellent yields, presumably via vinyliodine(III) intermediates.
M. Ochiai, K. Sumi, Y. Nagao, E. Fujita, M. Arimoto and H. Yamaguchi, J. Chem. Soc., Chem. Commun., 1985, 697 DOI: 10.1039/C39850000697
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