Intramolecular participation of π-electrons controls the AgI-assisted heterolysis of unsaturated cyclic N-chloroamines; molecular rearrangement of a rigid N-chioroamine occurs in the absence of AgI with involvement of a suitably-oriented π-bond.
M. L. Durrant, J. R. Malpass and M. P. Walker, J. Chem. Soc., Chem. Commun., 1985, 687 DOI: 10.1039/C39850000687
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