Rearrangement of N-chloro-2-azabicyclo[2.2.1]heptanes, [2.2.1]hept-5-enes, and [2.1.1]hexanes involving 1,2-migration of an sp3 or an sp2 carbon to nitrogen accompanied by 2,1-migration of chlorine occurs cleanly and efficiently on chromatographic alumina.
J. W. Davies, J. R. Malpass and M. P. Walker, J. Chem. Soc., Chem. Commun., 1985, 686 DOI: 10.1039/C39850000686
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