Issue 9, 1985

Co-ordination chemistry at a triply bridging site of [Pd33-CO)(µ-Ph2PCH2PPh2)3]2+: the structure of the chloride adduct

Abstract

The selective attachment of halide ions to a triply bridging site in the complex cation [Pd33-CO)(µ-dppm)3]2+(dppm = Ph2PCH2PPh2) has been established and the structure of the chloride adduct determined; the chloride ligand is very weakly bound to the Pd3 unit and is shielded by a ring of phenyl groups from the dppm ligands.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1985, 536-537

Co-ordination chemistry at a triply bridging site of [Pd33-CO)(µ-Ph2PCH2PPh2)3]2+: the structure of the chloride adduct

L. Manojlović-Muir, K. W. Muir, B. R. Lloyd and R. J. Puddephatt, J. Chem. Soc., Chem. Commun., 1985, 536 DOI: 10.1039/C39850000536

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