SCHEDULED MAINTENANCE
Secondary α-D and β-D6 equilibrium isotope effects are calculated by ab initio MO methods for gas-phase heterolyses of a range of 2-propyl substrates; an anomalous trend in the β-D6 effects with variation of the leaving group is accounted for by a model involving hyperconjugative and inductive contributions.
I. H. Williams, J. Chem. Soc., Chem. Commun., 1985, 510 DOI: 10.1039/C39850000510
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