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Issue 8, 1985
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Synthesis of a cyclic chiral axially disymmetric tetramethylethylenediamine-like but non chelating 1,2-diamine

Abstract

The diamine (S)-(3), obtained by treatment of (S)-1,1′-binaphthyl-2,2′-dicarboxylic acid chloride with N,N′-dimethylethylene-1,2-diamine, is evaluated as a chiral catalyst for addition of n-butyl-lithium to benzaldehyde, but leads to racemic 1-phenylpentan-1-ol, which is interpreted as a failure to complex the BunLi.

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Article information


J. Chem. Soc., Chem. Commun., 1985, 508-509
Article type
Paper

Synthesis of a cyclic chiral axially disymmetric tetramethylethylenediamine-like but non chelating 1,2-diamine

N. Maigrot and J. Mazaleyrat, J. Chem. Soc., Chem. Commun., 1985, 508 DOI: 10.1039/C39850000508

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