A simple hydrocarbon electrolyte: completing the electron-transfer series [Fe4S4(SPh)4]1–/2–/3–/4–
Abstract
Electrochemical properties of {[NBun4][BF4]·3 toluene} are described; the hydrocarbon medium allows, for the first time, the observation of all members of the [Fe4S4(SPh)4]n– electron-transfer Series, n= 1–4.