SCHEDULED MAINTENANCE
13 C-Labelling studies on a Rh–Ti/SiO2 catalyst using 13CO and 13CH3OH revealed that in a CO–H2 reaction C2-oxygenates such as ethanol are formed from a common precursor e.g. acyl, being formed by CO insertion onto surface CH3/CH2 moieties derived from CO dissociation and the subsequent reaction of the carbon product with hydrogen.
M. Ichikawa and T. Fukushima, J. Chem. Soc., Chem. Commun., 1985, 321 DOI: 10.1039/C39850000321
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