The solvolysis of N-acetoxy-2-acetylaminofluorene in aqueous acetone at neutral pH proceeds exclusively with nitrenium ion formation while under the same conditions, the 4-aminobiphenyl analogue exclusive acyl–oxygen scission.
G. R. Underwood and R. B. Kirsch, J. Chem. Soc., Chem. Commun., 1985, 136 DOI: 10.1039/C39850000136
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