18  O isotopic shifts in the 31P n.m.r. spectra of five-co-ordinate oxyphosphoranes

Paul B. Kay; Stuart Trippett

doi:10.1039/C39850000135

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¹⁸O isotopic shifts in the ³¹P n.m.r. spectra of five-co-ordinate oxyphosphoranes

Paul B. Kay and Stuart Trippett

Abstract

Apical and equatorial ¹⁸O produce different isotopic shifts in the ³¹P n.m.r. spectra of oxyphosphoranes; this difference can be used to follow permutational isomerisation by means of variable temperature ³¹P n.m.r. spectroscopy.

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DOI: https://doi.org/10.1039/C39850000135
Article type: Paper

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J. Chem. Soc., Chem. Commun., 1985, 135-136

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¹⁸ O isotopic shifts in the ³¹P n.m.r. spectra of five-co-ordinate oxyphosphoranes

P. B. Kay and S. Trippett, J. Chem. Soc., Chem. Commun., 1985, 135 DOI: 10.1039/C39850000135

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Journal of the Chemical Society, Chemical Communications