The regioselectivity observed in the formation of the iminocobaltacyclobutenes (3) from the substituted-acetylene complex (1) and the isocyanide (2) has been shown to be due to the electronic effect of substituents on the acetylene; skeletal rearrangement of the metallacycle had proved that the complexes (3) are the kinetically controlled products.
Y. Wakatsuki, S. Miya, S. Ikuta and H. Yamazaki, J. Chem. Soc., Chem. Commun., 1985, 35 DOI: 10.1039/C39850000035
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