Issue 1, 1985
From the journal:

Journal of the Chemical Society, Chemical Communications

Synthetic use of lithium nitride, an unusual reducing agent. Formation of Ti4 and Ti6 complexes

Melvyn Kilner,   Gerard Parkin  and  Andrew G. Talbot  

Abstract

Lithium nitride acts as a reducing agent in co-ordinating solvents librating dinitrogen, reducing TiCl4 to LiTiCl4(THF)4(THF = tetrahydrofuran), (η5-C5H5)2TiCl2 to [(η5-C5H5)2TiCl]2 and (C5H5)6Ti6(C5H4)2N, and (η5-C5H5)TiCl3 to (η5-C5H5)TiCl2(THF), [(η5-C5H5)TiCl2]n, and(C5H5)6(c5H4)2Ti6N3; in the presence of CO, Li3N reacts with (η5-C5H5)2TiCl2(2:3 molar ratio) to form (η5-C5H5)2Ti(CO)2.

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Article information

DOI
https://doi.org/10.1039/C39850000034
Article type
Paper

J. Chem. Soc., Chem. Commun., 1985, 34-35

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Synthetic use of lithium nitride, an unusual reducing agent. Formation of Ti4 and Ti6 complexes

M. Kilner, G. Parkin and A. G. Talbot, J. Chem. Soc., Chem. Commun., 1985, 34 DOI: 10.1039/C39850000034

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