Flash photolysis of Cr(CO)6 in H2-saturated cyclohexane Solution leads to the formation of Cr(CO)5(H2) as a relatively stable transient (k= 2.5 s–1 at room temperature); Cr(CO)5(H2) is identified by kinetic i.r. spectroscopy, including D2 isotpe effects.
S. P. Church, F. Grevels, H. Hermann and K. Schaffner, J. Chem. Soc., Chem. Commun., 1985, 30 DOI: 10.1039/C39850000030
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