[Cr(CO)5(H1)](1) is synthesized by u.v. photolysis of [Cr(CO)6] dissolved in liquid Xe doped with H2 at 200 K and the co-ordinated molecular dihydrogen has a νH–H i.r. band at 3030 cm–1; [Cr(CO)5(H2)] can also be generated photochemically in n-heptane at room temperature under high pressures (100 atm) of H2.
R. K. Upmacis, G. E. Gadd, M. Poliakoff, M. B. Simpson, J. J. Turner, R. Whyman and A. F. Simpson, J. Chem. Soc., Chem. Commun., 1985, 27 DOI: 10.1039/C39850000027
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