Reactivity of photophido-bridged heterobinculear complexes: site-selective carbonyl substitution by a hydride. Synthesis and structural characterisation of NEt4[H(CO)3Ru(µ-PPh2)Co(CO)3]

Salaheddine Guesmi; Georg Süss-Fink; Pierre H. Dixneuf; Nicholas J. Taylor; Arthur J. Carty

doi:10.1039/C39840001606

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Reactivity of photophido-bridged heterobinculear complexes: site-selective carbonyl substitution by a hydride. Synthesis and structural characterisation of NEt₄[H(CO)₃Ru(µ-PPh₂)Co(CO)₃]

Salaheddine Guesmi, Georg Süss-Fink, Pierre H. Dixneuf, Nicholas J. Taylor and Arthur J. Carty

Abstract

The phosphido-bridged heterobinuclear compound (CO)₄Ru(µ-PPh₂)Co(CO)₃(1) on treatment with NaBH₄ affords, via site-selective CO displacement on the ruthenium atom, the anion [H(CO)₃Ru(µ-PPh₂)Co(CO)₃]^– which contains a terminal hydride cis to a µ-PPh₂ group: the structure of the anion has been established by an X-ray diffraction study of the Et₄N⁺ salt.

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DOI: https://doi.org/10.1039/C39840001606
Article type: Paper

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J. Chem. Soc., Chem. Commun., 1984, 1606-1608

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Reactivity of photophido-bridged heterobinculear complexes: site-selective carbonyl substitution by a hydride. Synthesis and structural characterisation of NEt₄[H(CO)₃Ru(µ-PPh₂)Co(CO)₃]

S. Guesmi, G. Süss-Fink, P. H. Dixneuf, N. J. Taylor and A. J. Carty, J. Chem. Soc., Chem. Commun., 1984, 1606 DOI: 10.1039/C39840001606

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Journal of the Chemical Society, Chemical Communications

Reactivity of photophido-bridged heterobinculear complexes: site-selective carbonyl substitution by a hydride. Synthesis and structural characterisation of NEt₄[H(CO)₃Ru(µ-PPh₂)Co(CO)₃]

Abstract

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Reactivity of photophido-bridged heterobinculear complexes: site-selective carbonyl substitution by a hydride. Synthesis and structural characterisation of NEt₄[H(CO)₃Ru(µ-PPh₂)Co(CO)₃]

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