Lithium triethylhydridoborate acts as a stereospecific trisalkylating agent toward B5H9 producing exlusively 2,3,4-triethylpentaborane(9), while lithium tri(s-butyl)hydridoborate produces only the monoalkyl product 2-(s-butyl)pentaborane(9).
D. F. Gaines and G. A. Steehler, J. Chem. Soc., Chem. Commun., 1984, 1127 DOI: 10.1039/C39840001127
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