The oxidative doping of thin films of poly(p-phenylene sulphide) by arsenic pentafluoride has been followed by transmission absorption spectroscopy (near i.r. to u.v.) and transitions are assigned involving cationic states, poloran and bipolaron, formed within the π–π* band gap.
R. H. Friend and J. R. M. Giles, J. Chem. Soc., Chem. Commun., 1984, 1101 DOI: 10.1039/C39840001101
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