The crystal structure of the title complex shows an MCl4M bridge across a weak Ta–Ta interaction and eight-fold co-ordination about each metal centre; an electronic structure calculation supports the existence of a σ metal–metal bond.
P. D. W. Boyd, T. C. Jones, A. J. Nielson and C. E. F. Rickard, J. Chem. Soc., Chem. Commun., 1984, 1086 DOI: 10.1039/C39840001086
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