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Issue 11, 1984
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Synthesis of anionic sandwich compounds: [Ti(η-C6H5R)2] and the crystal structure of [K(18-crown-6)(µ-H)Mo(η-C5H5)2]

Abstract

Treatment of Mo(µ-C5H5)2H2 with potassium hydride and 18-crown-6 gives the compound [k(18-crown-6)(µ-H)Mo(η-C5H5)2] whose crystal structure has been determined; the compounds Ti(η-C6H5R)2, R = H or Me undergo reduction with potassium metal to give the salts K+[Ti(η-C6H5R)2], R = H or Me.

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Article type: Paper
DOI: 10.1039/C39840000729
Citation: J. Chem. Soc., Chem. Commun., 1984,0, 729-731
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    Synthesis of anionic sandwich compounds: [Ti(η-C6H5R)2] and the crystal structure of [K(18-crown-6)(µ-H)Mo(η-C5H5)2]

    J. A. Bandy, A. Berry, M. L. H. Green, R. N. Perutz, K. Prout and J. Verpeaux, J. Chem. Soc., Chem. Commun., 1984, 0, 729
    DOI: 10.1039/C39840000729

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