Issue 11, 1984
From the journal:

Journal of the Chemical Society, Chemical Communications

Reaction of M(C5Me5)2(OEt2), M = Eu or Yb, with phenylacetylene; formation of mixed-valence Yb3(C5Me5)4(µ-C[triple bond, length as m-dash]CPh)4 and Eu2(C5Me5)2(µ-C[triple bond, length as m-dash]CPh)2(tetrahydrofuran)4

James M. Boncella,   T. Don Tilley  and  Richard A. Andersen  

Abstract

Reaction of yb (C5Me5)2(OEt2) with PhC[triple bond, length as m-dash]CH yields the mixed-valence complex Yb3(C5Me5)4(µ-C[triple bond, length as m-dash]CPh)4 though Eu(C5Me5)2(OEt2) reacts with PhC[triple bond, length as m-dash]CH to give the divalent complex Eu2(C5Me5)2(µ-C[triple bond, length as m-dash]CPh)2(thf)4(thf = tetrahydrofuran)after crystallization from thf.

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Article information

DOI
https://doi.org/10.1039/C39840000710
Article type
Paper

J. Chem. Soc., Chem. Commun., 1984, 710-712

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Reaction of M(C5Me5)2(OEt2), M = Eu or Yb, with phenylacetylene; formation of mixed-valence Yb3(C5Me5)4(µ-C[triple bond, length as m-dash]CPh)4 and Eu2(C5Me5)2(µ-C[triple bond, length as m-dash]CPh)2(tetrahydrofuran)4

J. M. Boncella, T. D. Tilley and R. A. Andersen, J. Chem. Soc., Chem. Commun., 1984, 710 DOI: 10.1039/C39840000710

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