Issue 7, 1984

The reactions of cerium (IV) ammonium nitrate and cobalt (III) acetate with 1,2-diphenylethanes in acetic acid. Evidence against the involvement of radical cations in the side-chain oxidation of alkylbenzenes by Co(OAc)3

Abstract

The oxidation of 1,2- diphenylethane and 2,3-dimethyl-2,3-diphenylbutane by cerium(IV) ammonium nitrate and Co(OAc)3 in acetic acid show that a radical cation mechanism is plausible only in the reaction of the former oxidant.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1984, 445-446

The reactions of cerium (IV) ammonium nitrate and cobalt (III) acetate with 1,2-diphenylethanes in acetic acid. Evidence against the involvement of radical cations in the side-chain oxidation of alkylbenzenes by Co(OAc)3

E. Baciocchi and R. Ruzziconi, J. Chem. Soc., Chem. Commun., 1984, 445 DOI: 10.1039/C39840000445

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