Issue 6, 1984
From the journal:

Journal of the Chemical Society, Chemical Communications

A boroxine-supported triosmium oxymethylidyne cluster system, [(µ-H)3(CO)9Os3CO]3(B3O3): its structure and its conversion into halogeno- and phenyl-methylidyne complexes

Sheldon G. Shore,   Deng-Yang Jan,   Wen-Liang Hsu,   Leh-Yeh Hsu,   Steven Kennedy,   J. C. Huffman,   Tao-Chin Lin Wang  and  Alan G. Marshall  

Abstract

From the hydroboration of the unsaturated cluster (µ-H)2Os3(CO)10 in the presence of tetrahydrofuran, a cluster system was prepared with boroxine (B3O3) supporting three triosmium units, which was shown to be a useful starting material in the synthesis of the triosmium methylidyne clusters, (µ-H)3(CO)9Os3(CCl), (µ-H)3(CO)9Os3(CBr), and (µ-H)3(CO)9Os3(CPh).

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Article information

DOI
https://doi.org/10.1039/C39840000392
Article type
Paper

J. Chem. Soc., Chem. Commun., 1984, 392-394

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A boroxine-supported triosmium oxymethylidyne cluster system, [(µ-H)3(CO)9Os3CO]3(B3O3): its structure and its conversion into halogeno- and phenyl-methylidyne complexes

S. G. Shore, D. Jan, W. Hsu, L. Hsu, S. Kennedy, J. C. Huffman, T. L. Wang and A. G. Marshall, J. Chem. Soc., Chem. Commun., 1984, 392 DOI: 10.1039/C39840000392

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