Hexametallic clusters have been prepared and characterized in which the Hg–Co(CO)4 or Hg–Mo(CO)3(η-C5H5) fragment is µ3-bonded below the C03 face of the MCo3(M = Fe, Ru) tetrahedral precursor species; the structure of RuCo3(µ-CO)3(CO)9[µ3-HgCo(CO)4] has been determined by X-ray diffraction.
P. Braunstein, J. Rosé, A. Tiripicchio and M. Tiripicchio-Camellini, J. Chem. Soc., Chem. Commun., 1984, 391 DOI: 10.1039/C39840000391
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