Issue 6, 1984

Novel co-ordination modes for bimetallic HgCo and HgMo fragments when bonded to clusters; X-ray crystal structure of RuCo3(µ-CO)3(CO)93-HgCo(CO)4]

Abstract

Hexametallic clusters have been prepared and characterized in which the Hg–Co(CO)4 or Hg–Mo(CO)3(η-C5H5) fragment is µ3-bonded below the C03 face of the MCo3(M = Fe, Ru) tetrahedral precursor species; the structure of RuCo3(µ-CO)3(CO)93-HgCo(CO)4] has been determined by X-ray diffraction.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1984, 391-392

Novel co-ordination modes for bimetallic HgCo and HgMo fragments when bonded to clusters; X-ray crystal structure of RuCo3(µ-CO)3(CO)93-HgCo(CO)4]

P. Braunstein, J. Rosé, A. Tiripicchio and M. Tiripicchio-Camellini, J. Chem. Soc., Chem. Commun., 1984, 391 DOI: 10.1039/C39840000391

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