SCHEDULED MAINTENANCE
The simple air Oxidation of 1-phenyl-1-diazopent-ene derivatives (2) under basic conditions (NaH) was found to involve an efficient intramolecular epoxidation to give epoxyketone (3), while the dye-sensitised photo-oxygenation reaction of (2) afforded ketone (4) exclusively.
T. Miyashi, M. Kamata, Y. Nishizawa and T. Mukai, J. Chem. Soc., Chem. Commun., 1984, 147 DOI: 10.1039/C39840000147
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