Issue 3, 1984

Crystal engineering via Cl ⋯ Cl non-bonded interactions. The novel 2 : 1 complex, 6-chloro-3,4-(methylenedioxy)cinnamic acid–2,4-dichlorocinnamic acid. Topochemical conversion into an unsymmetrical cyclobutane and kinetics of the reaction

Abstract

Two chloro-subsitituted cinnamic acids have been induced to co-crystallise as a molecular complex which is converted, at different rates, into an unsymmetrical and two symmetrical cyclobutanes during solid-state topochemical 2 + 2 photoaddition.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1984, 145-147

Crystal engineering via Cl ⋯ Cl non-bonded interactions. The novel 2 : 1 complex, 6-chloro-3,4-(methylenedioxy)cinnamic acid–2,4-dichlorocinnamic acid. Topochemical conversion into an unsymmetrical cyclobutane and kinetics of the reaction

J. A. R. P. Sarma and G. R. Desiraju, J. Chem. Soc., Chem. Commun., 1984, 145 DOI: 10.1039/C39840000145

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