Issue 1, 1984
From the journal:

Journal of the Chemical Society, Chemical Communications

Synthesis of homo and hetero palladium–platinum bimetallic complexes; X-ray crystal structure of Pt2Cl2(µ-CO)(PPh3)3

Robert Bender,   Pierre Braunstein,   Antonio Tiripicchio  and  Marisa Tiripicchio-Camellini  

Abstract

The compounds M1(CO)(PPh3)3(M1= Pt, Pd) react with M2Cl2(PhCN)2(M2= Pt, Pd) in tetrahydrofuran at room temperature to afford the new homo [M1= M2= Pt (1); M1= M2= Pd (2)] or hetero [M1= Pt, M2= Pd (3); M1= Pd, M2= Pt(4)] bimetallic complexes M1M2Cl2(µ-CO)(PPh3)3via formal oxidative-addition of the M2(II)–Cl bond at the M1(0) centre; complex (1) has been structurally characterized by X-ray diffraction.

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Article information

DOI
https://doi.org/10.1039/C39840000042
Article type
Paper

J. Chem. Soc., Chem. Commun., 1984, 42-43

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Synthesis of homo and hetero palladium–platinum bimetallic complexes; X-ray crystal structure of Pt2Cl2(µ-CO)(PPh3)3

R. Bender, P. Braunstein, A. Tiripicchio and M. Tiripicchio-Camellini, J. Chem. Soc., Chem. Commun., 1984, 42 DOI: 10.1039/C39840000042

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