Issue 1, 1984
From the journal:

Journal of the Chemical Society, Chemical Communications

Mercury(II) chloride bridging two rhodium atoms. Preparation and X-ray crystal structure of [Rh2(η-C5H5)2(µ-CO)(µ-Ph2PCH2PPh2)(µ-HgCl2)]

Felice Faraone,   Sandra Lo Schiavo,   Giuseppe Bruno  and  Gabriella Bombieri  

Abstract

The title compound has been obtained by treating [Rh2(η-C5H5)2(µ-CO)(µ-dppm)][dppm = bis(diphenylphosphino)methane] with HgCl2, and characterized by spectroscopic and X-ray analyses; it represents the first example of mercury(II) chloride bridging two transition metal atoms in a complex.

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Article information

DOI
https://doi.org/10.1039/C39840000006
Article type
Paper

J. Chem. Soc., Chem. Commun., 1984, 6-7

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Mercury(II) chloride bridging two rhodium atoms. Preparation and X-ray crystal structure of [Rh2(η-C5H5)2(µ-CO)(µ-Ph2PCH2PPh2)(µ-HgCl2)]

F. Faraone, S. L. Schiavo, G. Bruno and G. Bombieri, J. Chem. Soc., Chem. Commun., 1984, 6 DOI: 10.1039/C39840000006

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