Alkylcopper complexes add to diethyl ethenylphosphonate to afford phosphonic esters with the alkyl chain increased by two carbon atoms; analogously vinylcopper complexes afford γ,δ-unsaturated phosphonic esters with retention of configuration in the double bond.
F. Nicotra, L. Panza and G. Russo, J. Chem. Soc., Chem. Commun., 1984, 5 DOI: 10.1039/C39840000005
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