Issue 23, 1983
From the journal:

Journal of the Chemical Society, Chemical Communications

Interconversion of ethylidyne, ethylidene, vinyl, and ethylene groups at a dimetal centre; X-ray crystal structure of [PtW(µ-CO)2(PEt3)2(η-C2H4)(η-C5H5)][BF4]

M. Rasol Awang,   John C. Jeffery  and  F. Gordon A. Stone  

Abstract

Treatment of the ethylidyne complex [PtW(µ-CMe)(CO)2(PEt3)2(η-C5H5)] with HBF4·Et2O affords the salt [PtW(µ-CO)2(PEt3)2(η-C2H4)(η-C5H5)][BF4], structurally characterised by X-ray crystallography; other complexes are described, derived from [PtW(µ-CMe)(CO)2(PMe3)2(η-C5H5)], with platinum–tungsten bonds bridged by CHMe or C(R)[double bond, length half m-dash]CH2(R = H or Me) groups.

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Article information

DOI
https://doi.org/10.1039/C39830001426
Article type
Paper

J. Chem. Soc., Chem. Commun., 1983, 1426-1428

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Interconversion of ethylidyne, ethylidene, vinyl, and ethylene groups at a dimetal centre; X-ray crystal structure of [PtW(µ-CO)2(PEt3)2(η-C2H4)(η-C5H5)][BF4]

M. R. Awang, J. C. Jeffery and F. G. A. Stone, J. Chem. Soc., Chem. Commun., 1983, 1426 DOI: 10.1039/C39830001426

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