SCHEDULED MAINTENANCE
The hydrido-norbornadiene (nbd) complex RuHCl(nbd)(PPh3)2 exists in solution as a single isomer with a coplanar arrangement of metal, hydride, and an alkene π-bond, the requisite geometry for olefin insertion; the insertion to give an alkenyl is promoted by reaction with carbon monoxide that itself subsequently inserts to give an acyl derivative.
T. W. Dekleva and B. R. James, J. Chem. Soc., Chem. Commun., 1983, 1350 DOI: 10.1039/C39830001350
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