Issue 21, 1983

Rh44-PPh)2(cyclo-octa-1,5-diene)4. A doubly co-ordinatively unsaturated phosphinindene-bridged cluster without carbonyl ligands

Abstract

The new cluster Rh4(µ4-PPh)2(cod)4(cod = cyclo-octa-1,5-diene) has been prepared by the reaction of Li2PPh, with Rh2(µ-Cl)2(cod)2 or the reaction of Rh2(µ-PPh2)(µ-Cl)(cod)2 with Li[BHEt3] and has been spectroscopically and structurally characterized.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1983, 1251-1252

Rh44-PPh)2(cyclo-octa-1,5-diene)4. A doubly co-ordinatively unsaturated phosphinindene-bridged cluster without carbonyl ligands

E. W. Burkhardt, W. C. Mercer, G. L. Geoffroy, A. L. Rheingold and W. C. Fultz, J. Chem. Soc., Chem. Commun., 1983, 1251 DOI: 10.1039/C39830001251

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