The compound Mo2(OAr)2(CH2SiMe3)4(OAr = 2,6-dimethylphenoxide) undergoes the smooth loss of one equivalent of Me4Si in the presence of pyridine (py) to form an alkylidyne-hydride compound, Mo2(µ-H)(µ-CSiMe3)(CH2SiMe3)2(OAr)2(py)2; both compounds have been structurally characterised by X-ray crystallography.
T. W. Coffindaffer, I. P. Rothwell and J. C. Huffmann, J. Chem. Soc., Chem. Commun., 1983, 1249 DOI: 10.1039/C39830001249
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