Issue 19, 1983

Reversible hydrogenation of anthracene during complexation to cyclopentadienyliron: change in regioselectivity depending on the steric bulk of the cyclopentadienyl group

Abstract

Anthracene and dihydroanthracene react with (C5Me5)Fe(CO)2Br and AlCl3 to give a mixture of [(C5Me5)Fe(η6-9,10-dihydroanthracene)]+X and [(C5Me5)Fe(η6-1,2,3,4-tetrahydroanthracene)]+X(60:40) whereas under identical conditions, (C5H5)Fe(CO)2Cl gives only [(C5H5)Fe(η6-9,10-dihydroanthracene)]+X.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1983, 1115-1116

Reversible hydrogenation of anthracene during complexation to cyclopentadienyliron: change in regioselectivity depending on the steric bulk of the cyclopentadienyl group

V. Guerchais and D. Astruc, J. Chem. Soc., Chem. Commun., 1983, 1115 DOI: 10.1039/C39830001115

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