Issue 19, 1983

Benzoyl trifluoromethanesulphonate. A highly efficient benzoylating agent for sterically hindered hydroxy groups

Abstract

Reactions of benzoyl trifluoromethanesulphonate (BzOTf) with a variety of alcohols, including some with sterically hindered secondary and tertiary hydroxy goups, with phenolic compounds, and with 1,2-diols at low temperatures provide the corresponding benzoates in high yield.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1983, 1113-1115

Benzoyl trifluoromethanesulphonate. A highly efficient benzoylating agent for sterically hindered hydroxy groups

M. Koreeda and L. Brown, J. Chem. Soc., Chem. Commun., 1983, 1113 DOI: 10.1039/C39830001113

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