Two unusual modes of dimerization of 2-alkyl-6-methyl-4H-1,3-thiazin-4-ones were observed; one gave the linearly combined dimers (3) and the other led to the novel spiro-compound (4); the structure of one of the spiro-compounds (4a) was confirmed by X-ray crystallography.
Y. Yamamoto, S. Ohnishi, R. Moroi and A. Yoshida, J. Chem. Soc., Chem. Commun., 1983, 56 DOI: 10.1039/C39830000056
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