Because of its charge density, the Li+ from LiCl is expected to interact strongly with the hydroxy group in propan-1-ol; instead, a strong interaction occurs between Li+ and the two methylene groups of the alcohol, whereas only weak interaction occurs between the Li+ and the hydroxy or methyl group. I.r. and n.m.r. studies suggest that a complex is formed between lithium chloride and propan-1-ol.
S. F. Sun, J. Chem. Soc., Faraday Trans. 1, 1982, 78, 2765 DOI: 10.1039/F19827802765
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