Issue 23, 1982

On the mechanism of oxidation of p-nitrosophenol by nitric acid. A labelling study shows the proposed nitrodenitrosation mechanism to be untenable

Abstract

Oxidation of p-nitrosophenol by 15N-labelled nitric acid in 34% sulphuric acid (4.4 M) did not produce labelled p-nitrophenol, thereby showing the nitrodenitrosation scheme of Bazanova and Stotskii to be untenable; furthermore, the order of the oxidation in nitric acid is 0.67, not 1, as reported by earlier workers.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1982, 1353-1354

On the mechanism of oxidation of p-nitrosophenol by nitric acid. A labelling study shows the proposed nitrodenitrosation mechanism to be untenable

D. S. Ross, R. Malhotra and W. C. Ogier, J. Chem. Soc., Chem. Commun., 1982, 1353 DOI: 10.1039/C39820001353

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