The reaction of potassium superoxide with diethyl chlorophosphate in the presence of 18-crown-6 ether gave at least two oxidizing agents, one of which was electrophilic and used in the oxidation of alkenes, whilst the other, nucleophilic in type, was important in the oxidation of sulphoxides.
M. Miura, M. Nojima and S. Kusabayashi, J. Chem. Soc., Chem. Commun., 1982, 1352 DOI: 10.1039/C39820001352
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