Issue 21, 1982

Redox chemistry of dichlorophosphorus(V)tetraphenylporphine : isolation and characterization of a stable porphyrin ‘anion’ radical and possible evidence for internal electron transfer

Abstract

One-electron reduction of the title complex leads o an extremely stable ring-reduced radical which has been isolated and characterized; addition of a second electron leads to, among other products, the free base tetraphenylporphine via an internal electron transfer.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1982, 1279-1280

Redox chemistry of dichlorophosphorus(V)tetraphenylporphine : isolation and characterization of a stable porphyrin ‘anion’ radical and possible evidence for internal electron transfer

C. A. Marrese and C. J. Carrano, J. Chem. Soc., Chem. Commun., 1982, 1279 DOI: 10.1039/C39820001279

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