The cyclisation/rearrangement products 2,2,4,4-tetramethylpentane in deuterium on sintered films of Ir, Rh, Pd, and Pt, analysed by combined gas-liquid chromatography/mass spectrometry, show that chemisorbed carbene and carbyne species are not responsible.
J. K. A. Clarke, O. E. Finlayson and J. J. Rooney, J. Chem. Soc., Chem. Commun., 1982, 1277 DOI: 10.1039/C39820001277
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