Issue 21, 1982
From the journal:

Journal of the Chemical Society, Chemical Communications

Synthesis of the first ruthenium (III) high complex: novel {RuNO} 5 d electron and {RuNO} 7 d electron complexes

Krishna K. Pandey,   Sita R. Ahuja,   Narendra S. Poonia  and  Sudhakar Bharti  

Abstract

Nitrosyl chloride reacts with hydrated ruthenium trichlorilde in the presence of triphenylphosphine (Ru : PPh3= 1 : 8) to give the pink RuIIIhigh spin complex NH4[Ru(NO)Cl5], NH4Cl, and the green {RuNO} 7 d electron complex [Ru(NO)Cl2(PPh3)]2 which reacts with PPh3 to give the yellow {RuNO} 7 d electron complex Ru(NO)Cl2(PPh3)2.

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Article information

DOI
https://doi.org/10.1039/C39820001268
Article type
Paper

J. Chem. Soc., Chem. Commun., 1982, 1268-1269

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Synthesis of the first ruthenium (III) high complex: novel {RuNO} 5 d electron and {RuNO} 7 d electron complexes

K. K. Pandey, S. R. Ahuja, N. S. Poonia and S. Bharti, J. Chem. Soc., Chem. Commun., 1982, 1268 DOI: 10.1039/C39820001268

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