Bimetallic iron–rhodium anionic carbonyl clusters [Fe2Rh(CO)x]–(x= 10 or 11), [FeRh4(CO)15]2–, [Fe2Rh4(CO)16]2–, and [FeRh5(CO)16]–

Alessandro Ceriotti; Giuliano Longoni; Mario Manassero; Mirella Sansoni; Roberto Della Pergola; Brian T. Heaton; David O. Smith

doi:10.1039/C39820000886

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Bimetallic iron–rhodium anionic carbonyl clusters [Fe₂Rh(CO)_x]^–(x= 10 or 11), [FeRh₄(CO)₁₅]^2–, [Fe₂Rh₄(CO)₁₆]^2–, and [FeRh₅(CO)₁₆]^–

Alessandro Ceriotti, Giuliano Longoni, Mario Manassero, Mirella Sansoni, Roberto Della Pergola, Brian T. Heaton and David O. Smith

Abstract

The syntheses and interconversions of mixed iron–rhodium carbonyl clusters are described; a combination of X-ray analysis and multinuclear n.m.r. measurements allowed the structural characterisation of [FeRh₄(CO)₁₅]^2–, [FeRh₅(CO)₁₆]^–, and [Fe₂Rh₄(CO)₁₆]^2–, which can all be obtained from the unstable cluster, [Fe₂Rh(CO)_x]^–(x= 10 or 11).

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DOI: https://doi.org/10.1039/C39820000886
Article type: Paper

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J. Chem. Soc., Chem. Commun., 1982, 886-887

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Bimetallic iron–rhodium anionic carbonyl clusters [Fe₂Rh(CO)_x]^–(x= 10 or 11), [FeRh₄(CO)₁₅]^2–, [Fe₂Rh₄(CO)₁₆]^2–, and [FeRh₅(CO)₁₆]^–

A. Ceriotti, G. Longoni, M. Manassero, M. Sansoni, R. D. Pergola, B. T. Heaton and D. O. Smith, J. Chem. Soc., Chem. Commun., 1982, 886 DOI: 10.1039/C39820000886

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Journal of the Chemical Society, Chemical Communications

Bimetallic iron–rhodium anionic carbonyl clusters [Fe₂Rh(CO)_x]^–(x= 10 or 11), [FeRh₄(CO)₁₅]^2–, [Fe₂Rh₄(CO)₁₆]^2–, and [FeRh₅(CO)₁₆]^–

Abstract

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Bimetallic iron–rhodium anionic carbonyl clusters [Fe₂Rh(CO)_x]^–(x= 10 or 11), [FeRh₄(CO)₁₅]^2–, [Fe₂Rh₄(CO)₁₆]^2–, and [FeRh₅(CO)₁₆]^–

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