Formal additions of CIF to the SN triple bond in NSF3 and to the CN triple bond in CF3CN and (CN)2 are achieved by the system Cl2–HgF2; N-bromo-amines and -imines are isolated from RfCN–Br2–HgF2·NSF3 and CF3SCl–HgF2 gives SF5N(SCF3)2 in high yield.
A. Waterfeld and R. Mews, J. Chem. Soc., Chem. Commun., 1982, 839 DOI: 10.1039/C39820000839
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