Conversion of dinitrogen bound terminally at a mononuclelar molybdenum site into an imido-ligand (NH) and a secondary amine has been achieved by the reactions shown in Scheme 1; the mode of N–N cleavage and the retention of the four equatorial ligands may be characteristic of the reactions of nitrogenase.
W. Hussain, G. J. Leigh and C. J. Pickett, J. Chem. Soc., Chem. Commun., 1982, 747 DOI: 10.1039/C39820000747
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