Issue 13, 1982
From the journal:

Journal of the Chemical Society, Chemical Communications

An inverse kinetic isotope effect for the hydrogenation of norbornadiene by the [Ir(PPh3)2(OCMe2)2H2]+ ion and its dideuterio-analogue

Oliver W. Howarth,   Colin H. McAteer,   Peter Moore  and  George E. Morris  

Abstract

A stopped-flow kinetic study reveals a marker inverse kinetic isotope effect for the hydrogenation of bicyclo[2.2.1]hepta-2,5-diene(norbornadiene, nbd) by the [Ir(PPh3)2(OCMe2)2H2]+ Ion (1), and its dideuterio-analogue, and a detailed mechanism is proposed.

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Article information

DOI
https://doi.org/10.1039/C39820000745
Article type
Paper

J. Chem. Soc., Chem. Commun., 1982, 745-747

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An inverse kinetic isotope effect for the hydrogenation of norbornadiene by the [Ir(PPh3)2(OCMe2)2H2]+ ion and its dideuterio-analogue

O. W. Howarth, C. H. McAteer, P. Moore and G. E. Morris, J. Chem. Soc., Chem. Commun., 1982, 745 DOI: 10.1039/C39820000745

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