An X-ray crystal structure of Pd2Cl2(C10H16Cl)2(3), obtained by chloropalladation of (+)-car-2-ene (1), shows that overall trans-addition of Pd–Cl across the cyclopropane moiety has occurred.
Jan-E. Bäckvall and E. E. Björkman, J. Chem. Soc., Chem. Commun., 1982, 693 DOI: 10.1039/C39820000693
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