Issue 11, 1982
From the journal:

Journal of the Chemical Society, Chemical Communications

Synthesis and X-ray crystal structure of the cluster cation [Os4(µ2-H)3(CO)12(NCMe)2]+: an example of an unsupported butterfly Os4 geometry

Brian F. G. Johnson,   Jack Lewis,   William J. H. Nelson,   José Puga,   Paul R. Raithby,   Martin Schröder  and  Kenton H. Whitmire  

Abstract

The cation [Os4(µ2-H)3(CO)12(NCMe)2]+ has been obtained by electrochemical and chemical (with NOX,X = BF4 or PF6) oxidation of [Os4H3(CO)12]– in acetonitrile; the four Os atoms define a ‘butterfly’ configuration with all the CO and MeCN ligands bonded in a terminal fashion.

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Article information

DOI
https://doi.org/10.1039/C39820000610
Article type
Paper

J. Chem. Soc., Chem. Commun., 1982, 610-612

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Synthesis and X-ray crystal structure of the cluster cation [Os4(µ2-H)3(CO)12(NCMe)2]+: an example of an unsupported butterfly Os4 geometry

B. F. G. Johnson, J. Lewis, W. J. H. Nelson, J. Puga, P. R. Raithby, M. Schröder and K. H. Whitmire, J. Chem. Soc., Chem. Commun., 1982, 610 DOI: 10.1039/C39820000610

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