Issue 10, 1982
From the journal:

Journal of the Chemical Society, Chemical Communications

Diphenylacetylene as a variable electron donor: syntheses and X-ray crystal structures of [Co(C2Ph2)(MeCN)(PMe3)3]BPh4 and [Co(C2Ph2)(PMe3)3]BPh4

Brigitte Capelle,   André L. Beauchamp,   Michèle Dartiguenave  and  Yves Dartiguenave  

Abstract

Two cationic cobalt(I) complexes were prepared as their BPh4-salts by the reaction of diphenylacetylene with CoBr(PMe3)3 in the presence of NaBPh4; diphenylacetylene behaves as a 2-electron donor in [Co(C2Ph2)(MeCN)(PMe3)3]BPh4 isolated from acetone–acetonitrile mixtures, but as a 4-electron donor in [Co(C2Ph2)(PMe3)3]BPh4 obtained from acetone.

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Article information

DOI
https://doi.org/10.1039/C39820000566
Article type
Paper

J. Chem. Soc., Chem. Commun., 1982, 566-568

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Diphenylacetylene as a variable electron donor: syntheses and X-ray crystal structures of [Co(C2Ph2)(MeCN)(PMe3)3]BPh4 and [Co(C2Ph2)(PMe3)3]BPh4

B. Capelle, A. L. Beauchamp, M. Dartiguenave and Y. Dartiguenave, J. Chem. Soc., Chem. Commun., 1982, 566 DOI: 10.1039/C39820000566

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